Photoelectron spectroscopic study of carbon aluminum hydride cluster anions.
نویسندگان
چکیده
Numerous previously unknown carbon aluminum hydride cluster anions were generated in the gas phase, identified by time-of-flight mass spectrometry and characterized by anion photoelectron spectroscopy, revealing their electronic structure. Density functional theory calculations on the CAl5-9H- and CAl5-7H2- found that several of them possess unusually high carbon atom coordination numbers. These cluster compositions have potential as the basis for new energetic materials.
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ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 145 15 شماره
صفحات -
تاریخ انتشار 2016